WebSep 15, 2009 · The kinetics of asymmetric hydrogenation of methyl levulinate in the presence of the (COD)Ru(2-methylallyl) 2 –BINAP–HCl catalytic system was studied. The kinetic order in H 2, as well as in the catalyst, was found to be equal to 1, whereas the kinetic order in the substrate and HCl falled from 1 to 0 with increasing their starting … WebDec 1, 2004 · Thus, BINP is the most electron-rich system (ca. indole displays a very fast rate of ES especially at the 3-position), followed by BITIOP and BITIANP, while BIMIP is the most electron-poor ligand. The presence of the electron-releasing methyl groups also enhances the electron density on the heterocycle, and hence the connected …
Synthesis and structure of the chiral palladium–fullerene C60 and …
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